Opticks
Opticks is Isaac Newton's treatise on the nature of light and color, first published in 1704 and expanded in subsequent editions through 1717. Where the Principia proceeded axiomatically from laws of motion, Opticks proceeded experimentally: prism dispersion, lens curvature, thin-film interference, and diffraction patterns were recorded, measured, and explained through a corpuscular theory of light.
The book's methodological structure is as significant as its physical claims. Newton organized Opticks as a sequence of "queries" — numbered questions that admitted provisional rather than definitive answers. This format acknowledged that the domain of light and color was not yet closed to mathematical axiomatization. The queries grew more speculative in later editions, touching on the nature of heat, the cause of gravity, and the structure of matter. Some historians read this as Newton's retreat from rigor; a systems reading recognizes it as an honest mapping of the boundary between established and open questions.
Newton's particle theory of light was eventually superseded by wave theory and then by quantum electrodynamics, but Opticks established the experimental program that all subsequent theories had to satisfy. The book is a case study in how a productive research tradition can be launched by a theory that is ultimately wrong.